Abstract
Infrared spectra of [Co(NH3)6]3+, [Co(NH3)5X]2+ (X=F, Cl, Br and I), and trans- [Co(NH3)4X2]+ (X =Cl,Br) have been measured in the 4000-250 cm−1 region. In addition to the characteristic NH stretching and NH3 deformation vibrations, Co—ligand stretching and skeletal deformation vibrations have been observed near 500 cm−1 and near 300 cm−1, respectively. Normal coordinate treatment has been made and the observed frequencies have been quantitatively assigned on the basis of the potential energy distribution and L- matrix. The Co—ligand stretching force constant shows that this co-ordination bond should be appreciably covalent.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
