Abstract
Infrared spectra of matrix isolated tin and lead difluorides are reported. Bands have been assigned to the monomer and dimer species. An M-F stretching mode has been observed for both tin and lead tetrafluoride. The symmetry assignments of the observed bands are discussed for both the monomer and dimer. A third type of species was observed and is thought to result from the reaction of a trapped dimer and a metal atom. Valence force constants and thermodynamic functions were calculated for tin and lead difluoride monomers.
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