Abstract
Infrared spectra obtained for the title compound, (CH 3) 2CCH. CH 2Br, have revealed the co-existence of two rotational isomeric forms in the fluid phases, the geometrical structures of which cannot be ascertained by use of vibrational spectroscopy alone. The energy ditterence between the two isomers was found to be 1.1 kcal mol −1 (mean value) in the liquid state. Some of the i.r. fundamental bands were assigned using the characteristic absorption frequencies of localized group.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callMore From: Spectrochimica Acta Part A: Molecular Spectroscopy
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
