Infrared on-site heating for material extrusion additive manufacturing of carbon fiber filled polyphenylene sulfide and its nano-graphene-reinforced alternatives

Abstract

This study investigates the impact of infrared heating and annealing on the mechanical properties of carbon fiber-reinforced polyphenylene sulfide (CF-PPS) and graphene nanoplatelet (GNP)-reinforced CF-PPS composites in Material extrusion (MEX) additive manufacturing. GNP/CF-PPS composites are prepared by mechanically mixing CF-PPS plastic particles with GNP particles and subjecting them to infrared heating and annealing treatments during the three-dimensional (3D) printing process. Three-point bending tests assess the mechanical properties of the samples. The results reveal that the 0.03 wt.% GNP/CF-PPS sample, subjected to infrared heating followed by annealing, exhibits a 30% increase in bending strength compared to pure CF-PPS, demonstrating that the combined treatment significantly enhances mechanical performance. Microscopy observations using a Keyence VH7000 digital optical microscope and a scanning electron microscope (SEM) confirm that GNP addition and infrared irradiation lead to reduced surface roughness and fewer fracture cross-sectional pores. The interlayer bonding improves notably, indicating enhanced internal density and structural stability. Furthermore, differential scanning calorimetry analysis shows a 20% increase in crystallinity for heat-treated samples, contributing to better interlaminar bonding and reduced temperature gradients during printing. Finite element simulations using MATLAB and ABAQUS software corroborate these findings, demonstrating that infrared heating proves more effective than varying GNP content alone in reducing deformation, residual stress, and temperature differences during the MEX process. These results provide valuable insights into improving the mechanical properties and stability of MEX-manufactured large-dimensional composite materials through optimized thermal management.