Abstract
The infrared laser-induced sulfur hexafluoride-photosensitized decomposition of (chloromethyl)trimethylsilane affords chlorotrimethylsilane and ethene as major primary products, showing this reaction occurring via 1,2-Cl shift and methene expulsion. At conditions of higher effective temperature, decomposition of chlorotrimethylsilane and reactions between sulfur hexafluoride and Si-containing compounds become important.
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