Abstract
The synthesis of the solid adducts Me 3SnOH · Me 3 SnNCO, Me 3SnOH · Me 3SnNCS, Me 3SnOH · Me 3PbN 3, Ph 3SnOH · Ph 3SnN 3 is reported. The compounds have been investigated by infrared and Mössbauer spectroscopy. Their structure probably consists of polymeric OH-R 3Sn-X-R 3Sn(Pb) chains in which hydroxyl and pseudohalide (X) groups are bridging pentacoordinate tin atoms. In contrast to the triphenyl compound, the trimethyl derivatives show evidence of hydrogen bonding between adjacent chains.
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