Abstract
The ternary complex [Cu (AdeH) (Ade) (phen)2OH]2·2H2O has been prepared and compared with the binary complexes. The mixed ligand complex was characterized from elementary analysis and infrared spectra. From the shift of the aromatic carbonaliphatic nitrogen stretching in infrared spectra, it is expected that the amino group of adenine ligand would not coordinate to copper (II), and consequently, it is likely that N9 of adenine ligand coordinates to copper (II) in the mixed ligand complex. The triplet state electron spin resonance spectra of the mixed ligand complex were recorded and the results interpreted in terms of a dipole-dipole interaction between pairs of copper (II) ions in a dimeric complex.
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