Infrared Analysis and Effect of Nitrogen and Nitrous Oxide on the Glass Transition of Methanol Cryofilms.

Abstract

Methanol plays an important role in studying the structure and dynamics of hydrogen bonds in alcohols and other physiologically important compounds in the condensed state. The physical vapor deposition method and two-beam interferometry make it possible to study the structure of polyatomic molecules, the nature and character of intermolecular interactions, and the internal structure of various compounds. Thus, it becomes possible to analyze changes in the internal structure of substances near the points of their phase transitions and glass transitions at ultralow temperatures. In this work, we have studied the effect of nitrogen and nitrous oxide on the dependence of refractive indices of methanol on temperature and on structural-phase transformations upon heating from 16 to 160 K.