Abstract

Silicon oxynitride (SiON) films were deposited on p-type (100) silicon substrates by plasma enhanced chemical vapor deposition (PECVD), at the temperature of 300 °C, using silane (SiH 4), nitrogen (N 2), ammonia (NH 3) and laughing gas (N 2O) as gas precursors. The effects of the processing gas ratio of N 2O/(N 2 + NH 3) on the optical properties, microstructure and chemical bonding evolutions of SiON material, and the influences of silicon nano-crystallized structures on the optical performance of SiON-based rib-type optical waveguides were studied. Microstructure evolutions analysis and optical measurements indicated that the refractive index and the extinction coefficient could be precisely determined by controlling the N 2O/(N 2 + NH 3) ratio and the thermal annealing process. A greater density and dimension of silicon nano-crystallized structures resulted in more optical scattering effect phenomena occurring between the interface of silicon nano-crystallized structure and SiON matrix and more optical propagation loss.

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