Abstract

The oxidation of thermal barrier coating (TBC) specimens consisting of nickel-base superalloy, low-pressure plasma sprayed Ni–28Cr–6Al–0.4Y (wt.%) bond coatings and air plasma-sprayed 7.5 wt.% yttria stabilized zirconia top coatings was studied at 1050 °C in flows of O 2, and mixture of O 2 and 5%H 2O under atmospheric pressure. The TBC exhibits very low oxidation rate at 1050 °C in pure O 2 and the oxidation kinetics accords with parabolic law. The oxidation kinetics of TBC obeys almost linear law after long exposure times in the presence of 5% water vapor. Oxide formed along the bond coat and top coat interface after oxidation at 1050 °C in pure O 2 consisted of Al 2O 3, whereas interfacial scales formed after oxidation at 1050 °C in a mixture of O 2 and 5%H 2O were mainly composed of Ni(Al,Cr) 2O 4, NiO, Cr 2O 3 and Al 2O 3. It is suggested that the effect of water vapor on the oxidation of the NiCrAlY coating may be attributed to the increase in Ni and Cr ions transport.

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