Abstract
AbstractDynamically cured thermoplastic elastomers or thermoplastic vulcanizates (TPVs) are widely used nowadays for their unique characteristics. In this paper, gas phase ethylene–propylene–diene terpolymer (GEPDM)/Polypropylene (PP) TPVs with various crosslinking systems have been extensively studied to optimize the curative level in each crosslinking system with special reference to their mechanical properties. Optimized systems were compared for heat aging, recyclability, crosslink density, morphology studies, and dynamic mechanical analysis. Crosslinking by peroxide in the presence of triallyl cyanurate as a coagent gives best overall performance with reference to excellent heat aging behavior, tension set, and compatibility between GEPDM and PP. Conventional EPDM/PP system was also compared with GEPDM/PP system. GEPDM/PP system was found to exhibit better behavior in all respects. Significant correlations were obtained between delta torque values obtained from Moving Die Rheometer and modulus or cross link density of TPVs irrespective of the nature of crosslinking agent. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 102: 5463–5471, 2006
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