Abstract

The defects, micropores, and microcracks on the plasma electrolytic oxidation (PEO) coating severely affect the long-term anti-corrosion feature. Inclusion of additives in the electrolyte is a feasible and effective strategy to attain the more intact PEO coating. The PEO coatings are fabricated on AZ31B Mg alloys in an silicon-based electrolyte with Na3VO4 (OPEO), NaVO3 (MPEO), and V2O3 (VPEO), respectively, to explore the influence of additives on the corrosion resistance. MPEO sample has the smallest poriness and pore size unfolding the best anti-corrosion resistance, which is also consistent with the electrochemical analysis. Even after 336 h salt spray test, the MPEO coating exhibits the least corrosion. The excellent anti-corrosion performance of MPEO sample is the synergistic effect of inorganic salts and multiple metal oxides generated in the formation of PEO coating. Inclusion of inorganic salt with valence change metal is a feasible pathway to achieve the compact PEO coating since multiple metal oxides could be produced and deposited in the PEO coating during the fabrication.

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