Abstract
AbstractPotentiodynamic polarization and cyclic voltametry measurements were employed to study the effect of topical fluoride preparations on corrosion of silver amalgam alloy in synthetic saliva and aqueous fluoride solutions. Results support that small amounts of copper and indium alloyed to silver – tin amalgam enhance corrosion resistance considerably. Indiloy shifts both the open circuit potential and the anodic polarization curve to more positive potential values, this lead to a decreases in the current density. The weak activity of Indiloy as compared with Spheraloy is attributed to the fact that the amount of γ2 phase (tin–mercury) present in the former is much lesser than that present in the latter. Findings also show that fluoride solutions (NaF, SnF and SnF + HCI) enhance the dissolution rate of the investigasted alloys and the polarization curves illustrate the appearance of an active – passive transitions. This behaviour was discussed on the basis of complex formation. Cyclic voltammograms confirm the results obtained from the potentiodynamic polarization measurements and elucidate the anodic oxidation peaks of silver oxide and copper verifying the proposed mechanism.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.