Abstract
The aim of this study is to investigate the influence of the tacticity dependent microstructure on the ability of PVC to accumulate space charge. In this connection the Thermal Step Method developed at ‘Laboratoire d'Electrotechnique de Montpellier’ is used to measure space charge distribution in poled samples. Three PVC samples of different tacticity are studied. We show that the space charge increase substantially with isotacticity. An explanation to this phenomenon is also provided.
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