Influence of the North Atlantic Oscillation on δD and δ18O in meteoric water in the Armenian Highland

Abstract

The stable hydrogen (δD) and oxygen (δ18O) isotope composition of modern meteoric water are influenced by changes in global temperature, Rayleigh distillation processes, and moisture transport history. However, on a global scale the relative influence of these different meteorological variables is spatially heterogeneous. We collected daily precipitation samples from meteorological stations in the Armenian Highlands for a period of one year in order to determine the constraints on δD and δ18O and relationship to broader climatic conditions. These data are coupled with HYSPLIT back-trajectory analysis to determine how these compositions relate to moisture source and transport path. Multivariate analysis shows the strongest relationship between δD and δ18O and climate variables is temperature at the sampling site. Along with temperature, the intensity of the North Atlantic Oscillation, a pattern of atmospheric circulation which determines the strength and location of Northern Hemisphere midlatitude westerlies, is significant (p < 0.05) for both δ18O and δD values of precipitation. This correlation between NAO and isotopes in precipitation is also observed in four nearby GNIP stations from 2008 to 2015. Negative NAO phases are associated with weakened westerlies, which allows precipitation enriched in heavy isotopes from the Mediterranean and southerly sources to penetrate into the Armenian Highlands, whereas positive NAO phases are associated with stronger westerlies bringing more negative precipitation from the Black Sea. This relationship is most significant (p < 0.001) during the winter and spring months (December to May). These data demonstrate that paleo-archives of δD and δ18O in the Armenian Highlands could serve as a tool to measure changes in the NAO in the past, particularly when coupled with independent measurements of temperature.