Abstract

Based on the self-consistent linear response theory, the plasmon-energy absorption in linear atomic chain are studied by using the tight-binding approximation. Results indicate that the eigen-frequency of the plasmon is uninfluenced by the external electric potential, but the plasmon modes excited by various electric potentials are obviously different. Each mode of plasmon corresponds to one kind of eigen-charge distribution. When the plasmon mode is excited, the resonant charge will show a distribution characteristic the same as the one of eigen charge. And the plasmon mode can be precisely controlled by external electric potential if the eigen-charge distribution at such plasmon is known. The relationship between plasmon-energy absorption and atom number are also affected by the external electric potential. However, most of the other studies only show the normal case that the plasmon-energy absorption increases with the atom number increasing. Here, we demonstrate that the normal case commonly occurs under monotone increasing potential. And abnormal case may occur under monotone decreasing potential, ie, the plasmon-energy absorption will decrease with the atom number increasing. But, in the presence of arbitrary potential applied to the same atomic chain, the plasmon-energy absorption will always increase with the electron number increasing.

Highlights

  • Study of plasmon is one of the most attractive topics in the field of optoelectronics

  • We have studied the plasmon excitation in linear atomic chains based on the tight binding model and self-consistent linear response theory

  • If the eigen-charge distribution at each plasmon mode is given, the excitation of arbitrary plasmon mode can be controlled by external field

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Summary

Model and Theory

The model of linear atomic chain we consider here is shown, where Lx = (Na + 1)a is the length of the atomic chain, a is the distance between the nearest two atoms, Na is the atom number, Vexe−iωt is the time-dependent external electric potential, and Vex is the space-distribution part of the potential. Based on the tight-binding model and the mean field approximation, in spin-independent case, the one- band Hamiltonian of linear atomic chain system in the frequency space is. For finite linear atomic chain, the eigen energy En and the corresponding wave function ψn(l) can be written as. L(ω) shows a peak at plasmon frequency ω, and it should be noted that the energy absorption function depends on both the induced charge and the external potential.

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