Abstract

The influence of the composition of the acetonitrile-dimethyl sulfoxide solvent on the main thermodynamic characteristics (ΔG°, ΔH°, ΔS°) of the complexation between silver(I) and piperidine was studied by the calorimetric and potentiometric methods. Analysis of the obtained experimental material was carried out using the solvation approach based on the thermodynamic solvation characteristics of the reactants.

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