Influence of the composite surface structure on the peel strength of metallized carbon fibre-reinforced epoxy

Abstract

In this work, the effect of mechanical pre-treatment on the surface structure of carbon fibre-reinforced epoxy composites and on its peel strength of electroless/electroplated copper was investigated. Sandblasting with Al2O3 was used to pre-treat the composite surface. The parameters investigated were blasting time (3s, 6s and 9s) and nozzle distance to substrate (300mm and 500mm). A two-step metallization process was used for depositing copper coatings on the pre-treated composite surface. First, an eletroless plating process was used to deposit a thin layer on the surface. Second, an electroplating process was used to reinforce the thickness of the coating. Increased blasting intensity leads to a significant increase in surface roughness, which promotes mechanical anchoring effects of the coating. Scanning electron microscopy images and contact angle measurements confirm the results of the surface roughness. The adhesion of sandblasted composites, characterized by measuring the peel strength, is 10 times higher compared to untreated specimens. In addition to the mechanical anchoring mechanism the exposure of carbon fibres on the surface due to the blasting process promoted a stronger bonding to copper, due to the higher, electrical conductivity of the fibres in comparison to the matrix.