Abstract
For 3,7,13,17-tetramethyl-2,8,12,18-tetrabutylporphyrin, 5,15-diphenyl-3,7,13,17-tetramethyl-2,8,12,18-tetrabutylporphyrin, and the cyclophane dimer in which the monomeric porphyrin fragments are bound via meta positions of the benzene rings with two -O(CH2)3O- bridges, the kinetics of complexation with copper(II) acetate in acetonitrile and the base ionization in the presence of perchloric acid were studied. The reactivity of these compounds in complexation with the metal cation in acetonitrile correlates with their basicity.
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