Influence of the acid–basic character of oxide surfaces in dispersants effectiveness

Abstract

Physical–chemical surface character has been described as a determinant factor in adsorbing polyelectrolytes onto oxide surfaces. Since basically composed by hydroxyl groups, the acidity or basicity induced by the bulk lattice in such groups seems to be of great relevance in the adsorption process. The influence of such properties in the adsorption of polyacrylic acid derivated polymers onto SnO 2 and Al 2O 3 surfaces is, therefore, studied in this paper. Polyacrylate acid molecules are observed to hardly adsorb onto the SnO 2 surface but strongly adsorb, as reported previously, onto the alumina surface. This behavior is explained based on the pronounced difference in relation to the acidity of both surfaces and, in this sphere of thought, a basic polymer (Chitosan; CS) is discussed as a functional dispersant for powders with acid surface character, such as SnO 2. Zeta potential measurements showed that this polymer raises the SnO 2 potential to +30 mV without pH variations.