Abstract
High-efficiency pour point depressants (PPDs) for diesel fuel were obtained using a series of tetradecyl methacrylate-N-α-methacrylamide copolymers (C14MC-NMLR) with different molar ratios synthesized through radical polymerization of tetradecyl methacrylate (C14MC) and various forms of N-α-methacrylamide (NMLR, R = -phenyl, -naphthyl, -cyclohexyl, -14a, -16a, -18a). The copolymers were characterized by Fourier transform infrared spectroscopy, 1H nuclear magnetic resonance, and thermogravimetric analysis. Results showed that diesel treated with C14MC-NML-phenyl (9:1) and C14MC-NML-14a (6:1) presented better cold flow properties at 2000 ppm, and the reductions in cold filter-plug point (ΔCFPP) and solid point (ΔSP) were (23 and 10 °C) and (22 and 11 °C) at 2000 ppm, respectively. The depressive effects further improved after compounding. When they were combined at a 1:4 mass ratio, PPDC-6 presented the best depressive effects, and the ΔCFPP and ΔSP reached 25 and 11 °C at 1000 ppm dosage and 28 and 15 °C at 2000 ppm dosage, respectively. Additionally, the crystallization behavior and crystal morphology of each treated diesel were explored.
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