Abstract
The combined influence of temporal fluctuations and spatial heterogeneity on non-reactive solute transport mechanisms in porous media can be understood by performing simulations of steady and unsteady flow and transport in heterogeneous media. The study focuses on issues such as the degree of heterogeneity, correlation length, separation of the combined effects of temporal and spatial variations, and ergodicity conditions under unsteady flow conditions. It is shown that the effect of temporal variations on solute transport is masked by the strong effect of spatial heterogeneity. There is no obvious difference in plume shape between steady and unsteady flow conditions; the first and the second spatial moments of the plume of the unsteady-state flow condition fluctuate around the steady-state flow condition with the same period of oscillations as the input signal at small storage coefficient (S ≤ 0.001). At a relatively high standard deviation in hydraulic conductivity and a small storage coefficient, the unsteady flow condition sharpens the temporal variations in macrodispersion coefficients. The magnitude of the longitudinal macrodispersion coefficient under unsteady flow condition is almost doubled at the maximum values. However, the transverse macrodispersion coefficient fluctuates around zero. The Kubo number and Peclet number ranges are 1.2–64 and 10–250, respectively.
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