Abstract
The variation of discharge current pulses with the surface nature of electrodes has been investigated by producing discharge in the intense ionizing zone of two ozonizers (A&B) containing pure, dry air at a pressure of 4 & 10mm of mercury respectively. The course of reaction in the tube A showed that the periodic rise and fall of discharge counts through a series of recurrences whose amplitude varied randomly. During this reaction, steady potential, temperature of the electrolytic bath, counting time and pulse height were kept fixed. The phenomenon obtained for both the tubes is produced within a critical range of conditions. The results have been interpreted on the basis of activated adsorption at a temperature of 90 degree and 100 degree Centigrade and discussed on the theoretical grounds of change of surface resistivity upon the glass walls. Use of different coatings on annular surface in the same system with appropriate levels of electrolytic solution for a definite value of height-pulses and temperature, etc. shows significant variations in the discharge counts.
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