Abstract
The influence of supercritical solvent density on the pyrolysis of benzyl phenyl ether (BPE) in tetralin and supercritical toluene is interpreted in terms of transport limitations. Reaction at varying toluene densities highlighted the transport dependence of the BPE fission rate constant. The conversion of BPE decreased from 0.55 to 0.15 as the toluene density increased from 0.0 to 0.75. The yield and selectivity of BPE rearrangement products were also density dependent. These results were explained and modeled quantitatively in terms of the cage effect theory
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