Abstract
N-Nitrosamines can be considered as potential NO/NO + donors. Previous studies demonstrated that aromatic N-nitrosoureas and aromatic N-nitrosamines can act as donors of NO. The relation of the structures of N-nitrosamines, in particular of aliphatic N-nitrosamines, to the characteristics of release and capture of NO or its redox forms remains unclear. In this paper we show that aliphatic N-nitrosamines of 7-azabicyclo[2.2.1]heptanes can undergo N–NO bond cleavage, and we also postulate that N-nitrosamines which enhance N–NO bond cleavage have low rotational barriers with respect to the N–NO bonds.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
