Abstract

This study focuses on the use of waste cotton fiber from the textile industry to produce composites with unsaturated polyester and to evaluate the performance of glass (G) / cotton (C) fiber laminates, particularly their mechanical and dynamic mechanical properties. Distinct stacking sequences were studied but the overall fiber content was kept constant. In general, hybrid laminates exhibited intermediate mechanical properties compared to those of the pure laminates, and optimum performance was obtained when the glass fiber mats were placed on the surfaces of the composite. Furthermore, some hybrid laminates exhibited superior dynamic mechanical performance, even compared to the pure glass laminate. Lower tan delta peak height (related to better fiber-matrix interaction) values and higher Tg were reported for the [C/G/ G ¯]s and [G/C/ C ¯]s samples which, together with the [G/C/ G ¯]s sample, exhibited the best results for reinforcement effectiveness and loss modulus peak height. Therefore, it is found possible to partially replace the glass fiber by waste cotton fiber considering that the final product may be optimized for mechanical property, which requires glass fiber at the surface of the laminate, or for dynamic mechanical properties, that allows higher cotton fiber content.

Highlights

  • Composite materials, especially those with a polymeric matrix, are of considerable interest to researchers and engineers due to a wide range of combinations in material properties 1

  • An important drawback preventing wider exploitation of natural fibers is their hydrophilic character, which is incompatible with the hydrophobic character of the polymer matrix

  • An extra weight loss process is sometimes observed in some natural fibers in the 220-310 °C range related to the presence of hemicellulose, but this was not identified in the DTG of the cotton probably due to the low amount of hemicellulose present in this fiber . 9-11 According to Satyanarayana et al 9, the composition of cotton is ~90% cellulose, ~6% hemicellulose, and 4% extractives, lignin and waxes

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Summary

Introduction

Especially those with a polymeric matrix, are of considerable interest to researchers and engineers due to a wide range of combinations in material properties 1. The use of natural fibers, such as sisal, jute, curaua, ramie and cotton, in polymer composites has grown in recent years, due to material abundance, low cost and low density, and due to their renewable characteristics. These materials are less abrasive to processing equipment compared to synthetic fibers, which becomes very important when equipment costs are high 1-3. Major advantages of synthetic fibers over natural fibers include lower moisture absorption of the former and their better adhesion with the polymer matrix 4. Poor fiber/matrix interfacial adhesion is observed 2,5

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