Influence of SO3 on the MnOx/TiO2 SCR catalyst for elemental mercury removal and the function of Fe modification

Abstract

Elemental mercury (Hg0) is a highly hazardous pollutant of coal combustion. The low-temperature SCR catalyst of MnOx/TiO2 can efficiently remove Hg0 in coal-burning flue gas. Considering its sulfur sensitivity, the effect of SO3 on the catalytic efficiency of MnOx/TiO2 and Fe modified MnOx/TiO2 for Hg0 removal was investigated comprehensively for the first time. Characterizations of Hg-TPD and XPS were conducted to explore the catalytic mechanisms of Hg0 removal processes under different conditions. Hg0 removal efficiency of MnOx/TiO2 was inhibited irreversibly from 92% to approximately 60% with the addition of 50 ppm SO3 at 150 ℃, which resulted from the transformation of Mn4+ and chemisorbed oxygen to MnSO4. The existence of H2O would intensify the inhibitory effect. The inhibition almost disappeared and even converted to promotion as the temperature increased to 250 ℃ and above. Fe modification on MnOx/TiO2 improved the Hg0 removal performance in the presence of SO3. The addition of SO3 caused only a slight inhibition of 1.9% on Hg0 removal efficiency of Fe modified MnOx/TiO2 in simulated coal-fired flue gas, and the efficiency maintained good stability during a 12 h experimental period. This work would be conducive to the future application of MnOx/TiO2 for synergistic Hg0 removal.