Abstract
Ozonation has been widely used as a viable advanced oxidation process (AOP) for elimination of PAHs in waste activated sludge through effective sludge disintegration and abatement of organic pollutants. However, sludge organic matter (SOM) influences PAHs degradation during ozone treatment is still rarely understood. In this study, we investigated such an influence with the aid of solid-state 13C nuclear magnetic resonance (NMR) spectroscopy and the corresponding two-dimensional correlation analysis (2D-COS) strategy. The results showed that the degradation of SOM macromolecules in the order of aromatic substances > aliphatic carbon > α carbon > amides groups > O-alkyl upon ozone treatment. Moreover, the PAHs removal efficiency was positively correlated with the aromaticity of sludge (R2 = 0.84–0.98), while negative associated with its aliphaticity (R2 = 0.81–0.95). Lastly, humic acid (HA) was used as a proxy of aromatic SOM to further explore their interaction with PAHs in sludge matrix. The results revealed that freely dissolved (HA-D) and suspended particulates (HA-S) imposed distinctively different influence on ozone-based PAHs degradation. The HA-S facilitated the elimination of PAHs by 7.95 ± 0.11%, while those HA-D reduced the removal efficiency by 16.70 ± 0.13%.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
