Abstract

Al2O3-SiC-C refractory castables added with β-sialon/Ti(C, N) powders were prepared with silica sol and phenolic resin as binding agents at room temperature. The effects of β-sialon/Ti(C, N) powders, silica sol and phenolic resin on slag penetration and corrosion resistance as well as oxidation resistance of the refractory castables were investigated by X-ray diffraction, scanning electron microscopy and energy dispersive spectroscope. Corrosion resistance and oxidation resistance mechanisms of the Al2O3-SiC-C refractory castables were also discussed. The results showed that the castables obtained with silica sol as the binding agent at a temperature of 1450oC presented better oxidation resistance. The oxidation resistance and slag erosion resistance of the refractory castables could be improved by adding Ti(C, N)/β-sialon powders. Static crucible method and fractal dimension calculation result showed that the prepared castables possessed excellent slag erosion resistance.

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