Influence of SDS on the Lα-phases of siloxane surfactant swollen by glycerol

Abstract

The interaction between SDS and the swollen lamellar phase of an A-B-A type nonionic siloxane surfactant IM-22 in 60 % glycerol has been investigated with macroscopic phase observation, FF-TEM, SAXS, conductivity, and rheology experiments. Without addition of SDS, 20 % IM-22 forms highly swollen planar lamellar phase stabilized by strong thermal undulations. Upon addition of 1 mM SDS, the lamellae were transformed into giant multilamellar vesicles. The size of the vesicles decreases with increasing the amount of SDS below 5 mM whereas the number density of the vesicles increases. Further increasing the concentration of SDS leads to break of the vesicles. In this self-assembly transition process, the viscosity of the system exhibits maximum at 5 mM SDS, where the system owns property of gels. Conductivity measurements suggest that SDS starts to bind IM-22 at a concentration below 2 mM, but SAXS results reveal that the interlamellar spacings were not affected up to 5 mM. This was explained by the special interactions in this system. On the one hand, the ionization degree of SDS in 60 % glycerol is very low due to the low dielectric constant, which results in lower charge density in the lamellae. Therefore, thermal undulations dominate the electrostatic forces at SDS concentration below 5 mM. On the other hand, the mutual phobic nature of SDS with IM-22 allows break of the lamellae at higher SDS concentrations.