Abstract

AbstractThe direct and interactive effects of process variables, including the use of iso‐pentane as an inert condensing agent, on the rate of polymerization and main physical properties of linear low‐density polyethylene are studied using two different statistical methods. Response surface methodology (RSM) based on a three level five factor Box–Behnken design is used to generate the number of experimental runs. The generated dataset is used to develop the RSM and artificial neural network (ANN) models. The effect of the input on the dependent variables is studied using the 3D response surface of the developed RSM model. The developed models are statistically analyzed and compared to determine their performance capability. The ANN model marginally outperforms the RSM model based on the computed statistical parameters but provides less information on the variable interactions.

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