Abstract
The influence of pressure on the shape of both TG and controlled transformation rate thermal analysis (CRTA) traces is theoretically and experimentally illustrated. It is shown that this shape can be explained on the basis of kinetic considerations and consequently thermoanalytical data can be used to perform kinetic analysis of solid state reactions contrary to Paulik's statement. However it has been shown that CRTA traces are more sensitive than conventional non-isothermal curves to the effect of pressure of the gases self-generated in the reaction. This may be considered as an interesting argument to explain the advantages of the CRTA technique for discriminating between overlapping processes.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
