Abstract

Abstract The effect of surface treatment on silica agglomerate dispersibility was investigated. Precipitated silica powders were treated with a commercially available coupling agent Bis-(triethoxysilylpropyl)-tetrasulphane (TESPT) in a blender. Spherical agglomerates of known density were prepared and dispersed in styrene butadiene rubber (SBR) under controlled flow conditions. The erosion kinetics was monitored by measuring the reduction in size of parent agglomerate with time. Silica dispersibility was greatly enhanced upon surface treatment. The coupling agent used in surface treatment is known to reduce filler—filler interactions and therefore affects the intrinsic cohesivity of the powder. However powder surface treatment can also induce changes in agglomerate morphology and filler-liquid interactions. The work presented in this paper evidences such changes.

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