Abstract
The development of titanium foams with a low elastic modulus has increased their scientific and technological relevance due to the evident need to avoid stress shielding problems. In this work, we studied the synthesis and characterization of Ti-13Zr-13Ta-3Nb (wt.%) alloy foams which present high potential for biomedical applications. A Ti-Nb-Ta-Zr mixture was produced by mechanical alloying using a planetary mill. Ti alloy foams were obtained using NaCl as a space-holder (40, 50, and 60 v/v %) that was mixed with the metallic powders and compacted under 420 MPa stress. NaCl particles were removed from the green compacts by submerging samples in distilled water at 60 °C. The green compacts were sintered at 1300 °C for 3 h in Ar atmosphere. Powders and foams were characterized by SEM and optical microscopy. The results showed that Ti-based foams with a tailored heterogeneous pore distribution can be obtained using the space holder method. The elastic modulus (E) of foams was estimated and measured between 5 and 25 GPa using theoretical and finite element analysis (FEA) models which are close to the E values measured experimentally. The results showed that foams with 50% and 60% porosity are potential bone replacement materials because their E value is closer to the E value of human bone.
Highlights
Pure titanium and its alloys have been widely employed in aerospace, automotive, and biomedical applications due to their excellent combination of corrosion resistance, biocompatibility, and high specific mechanic strength [1]
The NaCl particle size ranges from 150 to 350 mm, which is an acceptable pore size for metallic foams used in biomedical applications
Ti-13Zr-13Ta-3Nballoy alloy foams were synthetized as a holder
Summary
Pure titanium and its alloys have been widely employed in aerospace, automotive, and biomedical applications due to their excellent combination of corrosion resistance, biocompatibility, and high specific mechanic strength [1]. Metals 2019, 9, 176 which can produce long-term health problems, such as Alzheimer’s disease [3], dermatitis, neuropathy, and ostemomalacia [4]. For this reason, V- and Al-free Ti-based alloys with alloying elements such as Nb, Zr, Sn, or Ta were explored for implant applications [2]. V- and Al-free Ti-based alloys with alloying elements such as Nb, Zr, Sn, or Ta were explored for implant applications [2] Among these already developed new titanium alloys, it is possible to find Ti-30Nb-13Ta-4.6Zr, Ti-35Nb-5Ta-7Zr, Ti-13Nb-14Zr [5], Ti-13Nb-13Zr, Ti-35Nb-7Zr-5Ta, Ti-Mo, Ti-29-Nb-13Ta-4.6Zr [4], and Ti-34Nb-29Ta-6Mn [6].
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