Abstract
AbstractThe influence of phenol on the habit of sodium chloride crystals was studied quantitatively. At small concentrations the presence of phenol has no influence whatsoever on the growth rate of the (100) face. At greater concentrations this growth rate increases. Spiral growth was observed on the (100) face by surface dissolution. Phenol slows down the growth rate of the (111) face, the energy barrier being about 600 cal/mole. Roughening of this face is observed when crystallization takes place from pure solutions and in the presence of small amounts of phenol. At a phenol concentration of 0.065 mole/l the growth rates of the (100) and (111) faces become equal.
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