Abstract

Influence of operating pressure on concentration polarization layer resistance in revers osmosis

Highlights

  • The experimental examination of hypothesis about linear dependence of concentration polarization resistance from pressure was carried out and the influence of hydrodynamic condition on this resistance is determined

  • The membrane resistance during reverse osmosis of deionized water did not change with applied pressure in experimental conditions and was equal Rm=7,549·1013 m-1

  • The concentration polarization layer resistance (Rcp) increased from 0.65–1.29·1013 m-1 to 1.46–1.83·1013 m-1 with applied pressure increasing from 0.2 MPa to 0.6 MPa and from 0.65–1.46 m-1 to 1.29–1.83·1013 m-1 with increasing of feed concentration from 100 mg/dm3 to 600 mg/dm3

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Summary

Materials and methods

Materials The experiments were carried out with using of commercially available reverse osmosis membrane modules Dow Filmtec TW30-1812-50 (made in USA). Since in membrane module the flow rate change with channel length due to penetration of a part of the feed solution through the membrane in present research the mean value calculated from the permeate and retentate flow rate was used as a determining velocity, m/s [27]: Lf Lr we (5). Determination of concentration polarization layer resistance The calculations of resistance were carried out based on transmembrane flux value which according to [12–14] can be described by equation, m3/(m2·s): Δp Δπ. Whereas the Rm is known, the concentration polarization resistance could be obtained from measurements results from dependency, found from the transformations of equations (7) and (8): Rcp. for the solution with known values of osmotic pressure and dynamic viscosity the concentration polarization layer resistance could be determinated experimentally. These values could be determinated from reference literature [30–31]

Results and discussion
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