Influence of oil and stratal water contamination on the ash composition of oligotrophic peat soils in the oil-production area (the Ob’ region)

Abstract

The mineral contamination of peat soils in the oil-production area differs considerably in the places of oil or stratal water spills. The time elapsed since the spill occurred is also an important factor of the changes in the chemical composition of the peat ash. The ash content rises drastically in the oil-contaminated peat, and the peat ash becomes rich in heavy metals (Mn, Ni, and Sr) and lanthanides (La and Ce). The content of K and Fe decreases, and that of P, S, Mg, Ca, Ni, and Pb increases with time at the site of old oil contamination. In the course of the self-rehabilitation of oil-contaminated peat, the content of Cl decreases more intensely than that of the heavier halogen Br. The ash content rises to a lesser extent in the peat contaminated with stratal water. The ash of the salinized peat is enriched in heavy alkaline-earth elements, i.e., Ba and Sr. Although most of the elements are leached with time, the content of Ba and Sr still remains 4–6 times higher than the background one even after long-term (more than 10 years) leaching. The concentrations of halogens rise considerably in the salinized peat, that of Cl in the peat ash decreases by 10 times, and the content of Ba virtually remains the same.