Abstract
This study evaluated the Knoop hardness (KH, N/mm2) and degree of conversion (DC, %) on the margins of light-cured resin cements with different photoinitiators using a single light-curing unit (LCU) with two heads (mono- and multiwave). Three types of resin cements were used with different photoinitiators: Megalink Esthetic (Odontomega, São Paulo, Brazil) with a camphorquinone photoinitiator; Allcem Veneer (FGM, Joinville, Brazil) with the Advanced Polymerization system (APS), and Variolink Esthetic LC (Ivoclar Vivadent, Schaan, Liechtenstein). Thirty samples were collected and divided into six groups (n=5 each). The resin cement samples were made into the shape of a maxillary right central incisor and photoactivated under a 0.5-mm-thick ceramic sheet. A single LCU (Radii Xpert, SDI) with two heads (mono- and multiwave) was used. The tip of the LCU was positioned at the center of the sample in a standardized manner. Raman spectroscopy was performed to evaluate the DC, and KH was evaluated through the Knoop microhardness test. Five regions were evaluated: cervical, mesial, buccal (center), distal, and incisal. There was a significant difference in the DC only for the type of cement (p<0.001), indicating that the cement with the APS photoinitiator presented excellent results. There were significant differences in the type of cement (p<0.001), type of light (p<0.001), region (p<0.001), and the interaction between the type of cement and type of light (p<0.001). The resin cement with the APS photoinitiator cured with monowave light showed the highest KH values. The beam profiles of all groups, with and without the interposition of ceramic and resin cement, were examined by light transmission. The cement with the APS photoinitiator presented the best results with respect to the DC and KH. In comparison with mono- and multiwaves, the LCU may not be a determining factor for the properties of light-cured resin cements. The buccal region showed the best results for DC and KH, indicating the need for a greater amount of light-curing at the cementation margins.
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