Influence of mesoporous phosphotungstic acid on the physicochemical properties and performance of sulfonated poly ether ether ketone in proton exchange membrane fuel cell

Abstract

This study demonstrates the successful development of hybrid mesoporous siliceous phosphotungstic acid (mPTA-Si) and sulfonated poly ether ether ketone (SPEEK) as a proton exchange membrane with a high performance in hydrogen proton exchange membrane fuel cells (PEMFC). SPEEK acts as a polymeric membrane matrix and mPTA-Si acts as the mechanical reinforcer and proton conducting enhancer. Interestingly, incorporating mPTA-Si did not affect the morphological aspect of SPEEK as dense membrane upon loading the amount of mPTA-Si up to 2.5 wt%. The water uptake reduced to 14% from 21.5% when mPTA-Si content increases from 0.5 to 2.5 wt% respectively. Meanwhile, the proton conductivity increased to 0.01 Scm −1 with 1.0 wt% mPTA-Si and maximum power density of 180.87 mWcm −2 which is 200% improvement as compared to pristine SPEEK membrane. The systematic study of hybrid SP-mPTA-Si membrane proved a substantial enhancement in the performance together with further improvement on physicochemical properties of parent SPEEK membrane desirable for the PEMFC application. • Incorporation of porous HPA in SPEEK membrane used as electrolyte layer in PEMFC. • Physical and chemical properties are being characterized to get the best membrane. • The performance analysis concluded the highest performing membrane.