Abstract
ABSTRACT To predict real-time performance of metal hydride-based systems, La0.9Ce0.1Ni5 and LaNi4.7Al0.3 alloys are opted to investigate the influence of operating temperature and supply pressure on absorption kinetics. For the same, the pressure ratio is varied from 1.5 to 4 by keeping the temperature constant. Later, the operating temperature is varied (20–80°C) for the above range of pressure ratio. The study revealed that the absorption kinetics of metal hydrides is substantially influenced by operating temperature and supply pressure. It is observed that with an increase in pressure ratio (1.5, 2, 2.5, 3, and 3.5), the hydrogen supply pressure increases (9.75, 13, 16.25, 19.5, and 22.75), which creates high driving potential consequently results in faster reaction rates. However, increase in operating temperature (20°C and 40°C) at constant supply pressure (25 bar) results in slower reaction rates due to decrease in driving potential because the equilibrium pressure of La0.9Ce0.1Ni5 is higher at high temperature. The similar effect is obtained for LaNi4.7Al0.3. The experimental measurements are carried out using an in-house Sievert’s apparatus and are compared with numerical results obtained through a mathematical model that results in good agreement.
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