Abstract
Influence of magnetic dilution with ZnII ions on the spin transition in the iron nitrate complex of 4-amino-1,2,4-triazole (AT) was studied by magnetochemistry, Mossbauer spectroscopy, and IR spectroscopy. In studies of the properties of solid phases of Fe x Zn 1−x (AT)3(NO3)2 (0.01≤x≤0.8), it was demonstrated that magnetic dilution results in a lowered spin transition temperature and an increased share of the high-spin form of the iron(II) complex.
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