Abstract

The electrical conductivity and mechanical strength of carbon nanotube (CNT) buckypaper comprised of millimeter-scale long single-walled CNT (SWCNT) was markedly improved by the use of longer SWCNTs. A series of buckypapers, fabricated from SWCNT forests of varying heights (350, 700, 1,500 μm), showed that both the electrical conductivity (19 to 45 S/cm) and tensile strength (27 to 52 MPa) doubled. These improvements were due to improved transfer of electron and load through a reduced number of junctions for longer SWCNTs. Interestingly, no effects of forest height on the thermal diffusivity of SWCNT buckypapers were observed. Further, these findings provide evidence that the actual SWCNT length in forests is similar to the height.

Highlights

  • The effective transfer of phonons, electrons, and load is known to increase with longer carbon nanotubes (CNTs) within CNT agglomerates

  • High electrical conductivity in buckypaper fabricated from high single-walled CNT (SWCNT) forests We found that buckypaper fabricated from tall SWCNT forests exhibited excellent electrical conductivity and mechanical strength

  • In order to verify that this apparent height-dependent variation in buckypaper conductivity was not due to differences in CNT quality, which has been shown to be essential for the various properties of buckypaper in previous works [34], Raman spectroscopy and electrical resistivity measurements of the as-grown SWCNT forests were carried out

Read more

Summary

Introduction

The effective transfer of phonons, electrons, and load is known to increase with longer carbon nanotubes (CNTs) within CNT agglomerates. Reported a field effect transistor (FET) with high mobility using long single-walled CNTs (SWCNTs) [7]. In CNT/polymer composites, the beneficial effect of CNT length on the efficiency of phonon/electron transport and interfacial load transfer has been reported [8,9,10,11]. Such superiority in properties from long CNTs originates from the fewer CNT junctions, which interrupt phonon, electron, and load transfer, in a network structure of CNTs required to span the material

Methods
Results
Conclusion

Talk to us

Join us for a 30 min session where you can share your feedback and ask us any queries you have

Schedule a call

Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.