Influence of ionic mobility on the phase transformation route in Y 3Al 5O 12 (YAG) stoichiometry

Abstract

Ionic mobilities of Y 3+ and Al 3+ are controlled using either amorphous or well-crystallized precursors and enhanced by the addition of molten NaCl flux. Experimental results indicate that phase transformation prefers a relatively slow reaction route via YAM–YAP–YAG because of limited ionic mobility when either Y 3+ or Al 3+ is confined to a crystallized structure. The selection of intermediate phases can be either Y-rich (YAM) or Al-rich (YAP), depending on the competition of ionic mobility between Y 3+ and Al 3+ during phase transformation. The YAH–YAG route is selected only when the ionic mobility of Y 3+ or Al 3+ is high enough to induce a nucleation and growth reaction while a certain degree of stoichiometric inhomogeneity is presented; otherwise YAG is crystallized directly from amorphous precursors without passing through any intermediate phase.