Abstract
Values of the B coefficient of the viscosity of the Jones–Dole equation are reported for sodium iodide in the water–t-butyl alcohol system up to 90 mol % t-butyl alcohol at 26 °C. The calculation of the theoretical A coefficient of the Jones–Dole equation needs the ionic limiting conductivity data. The conductivity measurements of Bu4NI and NaBPh4 solutions in water–t-butyl alcohol mixtures at 26 °C were performed in order to divide the conductivity for NaI, known from our earlier investigations, into ionic contributions. The division is based on the assumption of Fuoss et al. that Λ0(Bu4N+)= 0.519Λ0(Bu4NBPh4).
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Schedule a callMore From: Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases
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