Abstract
The anodic dissolution of Zn and Zn–5%In alloy was investigated in acid chloride and perchlorate solutions by means of polarisation curves and electrochemical impedance spectroscopy. The composition and morphology of surface attack were analysed by SEM/EDX. The presence of In, as a diluted solid solution in a rich Zn phase and as rich In phases segregated at grain boundaries, brings about a decrease of the rate of hydrogen evolution reaction. On the other hand, the strong interaction of In with OH − and Cl − at potentials more positive than −1.10 V vs SCE leads to an increase of the anodic dissolution rate of Zn near the corrosion potential. In perchlorate solutions, this is explained in terms of a reaction path involving the formation of the adsorbate ZnOH as an intermediate species. In chloride solutions, the more negative value of the potential of a zero charge of In allows Cl − to be adsorbed on Zn at more negative potentials increasing its oxidation rate.
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