Influence of hygrothermal aging on dimensional stability of thin injection‐molded short glass fiber reinforced PA6 materials

Abstract

ABSTRACTThe hygrothermal aging of short glass fiber reinforced polyamide 6 materials (PA6/GF) is a major problem for thin‐walled components used in the automotive sector. In this work, the thickness and glass fiber content of PA6/GF materials were varied and exposed to hygrothermal aging. The temperature and relative humidity were chosen to range from −40 to 85°C and 10% RH to 85% RH respectively, according to automotive requirements for components in the passenger compartment. For the absorption of moisture, the diffusion behavior could not be generally described by Fick's law. However, the results indicate that the diffusion behavior is dependent on the relative humidity and thickness of the PA6/GF material. The morphology of the test specimen, which is influenced by injection molding, was also found to affect the diffusion behavior. The states of equilibrium for moisture absorption are strongly dependent on the relative humidity during hygrothermal aging and less dependent on the temperature. The maximum absorbed humidity was found at a temperature of 65°C and 85% RH, which was higher than at 85°C and 85% RH because of reduced contrary aging processes, such as postcrystallization. In certain climatic conditions and test specimen thicknesses, there was a characteristic overshoot in the mass change. This behavior could be attributed to a different degree of crystallization and lower glass fiber content. Both moisture absorption and an overshoot of the mass affected the dimensional stability of the test specimens. This effect on dimensional stability could be correlated with the glass fiber orientation. © 2015 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2015, 132, 42245.