Abstract

In the present work, the hydrogen/material interaction with two austenitic steel types, created via a completely different alloying strategy, is investigated. The two steels include 304L austenitic stainless steel (ASS) and 18Mn-0.6C twinning-induced plasticity (TWIP) steel. Constant extension rate tensile tests are performed to evaluate the influence of hydrogen on the deformation and fracture mechanisms. A reference condition without hydrogen is compared to a seven days electrochemically hydrogen precharged condition. 304L ASS shows transformation to α’-martensite without hydrogen, while hydrogen increases the α’-martensite fraction and additionally enables the transformation to ε-martensite. The fracture surface has a transgranular, quasi-cleavage appearance. The TWIP steel shows deformation twinning without hydrogen, while abundant ε-martensite transformation is observed in the presence of hydrogen. The fracture type is intergranular due to the high cracking sensitivity of the grain boundaries.

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