Influence of Hydrocarbon Surfactant on the Aggregation Behavior of Silicone Surfactant: Observation of Intermediate Structures in the Vesicle−Micelle Transition

Abstract

Intermediate structures of the aggregates in the aqueous solution of an ABA-type silicone surfactant and in the process of an SDS-induced vesicle-micelle transition are reported. In single ABA silicone surfactant aqueous solutions, large multilamellar vesicles (MLV), small single lamellar vesicles (SLV), threadlike micelles (TLM), and spheroidal micelles were observed. Interestingly, a large amount of TLMs were found entrapped into the large MLVs, but not in SLVs. Disintegration of the small vesicles inside the MLVs indicates that the entrapped TLM are from the disintegrated membrane of the entrapped small vesicles. Addition of SDS induced a transition from vesicles or threadlike micelles to spheroidal micelles. The intermediate structures, such as the appearance of small holes in the vesicle membrane, the budding of threadlike micelles from the membrane fracture, and the clusters of spheroidal micelles, were observed with increase of the SDS concentration. The electrical conductivity measurements indicated that complex micelles of SDS and silicone surfactant were formed in the solution due to the interaction between the SDS and PEO part of the silicone surfactant.