Abstract
Optical absorption spectra of monolithic silica sol–gel glasses incorporating the lanthanide complexes [Ln(bpy)2]Cl3, [Ln(phen)2]Cl3 and Ln(NO3)3 (bpy = bipyridyl, 2,2'-bipyridine, phen = 1,10-phenanthroline, Ln = Nd, Sm, Dy, Ho, Er) were recorded. The Judd–Ofelt theory was used to study changes in the coordination sphere before and after water was expelled from the glass matrix by heat treatment. The intensity of the hypersensitive transitions was found to increase significantly, which is reflected by an increase in the Ω2 intensity parameter. The non-hypersensitive transitions are influenced by the native sol–gel matrix rather then by the type of ligands. The Ω4 and Ω6 parameters remain more or less constant upon heat treatment. In accordance with theoretical predictions the values of both Ω4 and Ω6 of the lighter lanthanides are larger than those of the heavy lanthanides.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.