Abstract

The rate of S oxidation in elemental S fertilizers to plant-available sulphate-S depends on factors that affect microbial activity, such as soil moisture, temperature, aeration and size of fertilizer granules. Three field experiments were conducted on S-deficient Gray and Dark Gray Luvisol soils (Typic Cryoboralf) during 2000 and 2001 in Saskatchewan (exp. 1 at Porcupine Plain and exp. 3 at Canwood) and Alberta (exp. 2 at Legal) to determine the effects of formulation of elemental S fertilizers on yield, oil, protein and S concentration, S uptake, percent recovery of applied S and N uptake in seed of canola (Brassica napus L. ‘A4573’ at Porcupine Plain and ‘Invigor 2663’ at Legal and Canwood). In exp. 1 (2000 and 2001) and exp. 2 (2000), treatments included five elemental S fertilizers (granular ES-99, ES-95, ES-90 and Biosul-90; and Biosul-50 suspension), granular potassium sulphate and zero-S control. In exp. 3, treatments included eight elemental S fertilizers (granular ES-99, ES-95, ES-90 and Biosul-90; powder Lab fine ES-99.5, ES Settle-47 and ES SPB571-85.8; and Biosul-50 suspension), 21.7% elemental S plus 18.7% sulphate-S (Agrium Plus), blend of granular ES-90 and ammonium sulphate (1:1), granular ammonium sulphate and zero-S control. The S fertilizers were surface-broadcast or sprayed at 15 and 30 kg S ha-1 rates within 2–3 d after sowing in spring. Canola plants in the zero-S treatment showed S deficiency in the growing season, and seed yield increased with sulphate-S fertilizer by 21.8, 1.4, and 3.6 times in exps. 1, 2, and 3, respectively. There was little effect of S fertilizer on protein concentration in seed. Biosul-50 suspension in all experiments and powder forms of elemental S fertilizers, used only in exp. 3, were almost as effective as sulphate-S fertilizers. In all experiments, granular elemental S fertilizers had no or only a very small effect on yield, S uptake, percent recovery of applied S, N uptake, oil concentration, S concentration and protein concentration of canola seed in the first year of application. In the second year of exp. 1, granular elemental S fertilizers tended to increase yield, S uptake, N uptake, oil concentration, and S concentration of canola seed, but none of them produced seed yield or improved other parameters of canola seed comparable with the sulphate-S and elemental S powder or suspension fertilizers. In summary, granular elemental S fertilizers were not effective in increasing canola seed yield and S uptake on S-deficient soils in the first year of application. After the second annual application, most granular elemental S fertilizers tended to correct deficiency of S in canola plants, but improvements in yield and other parameters of seed were still less than the sulphate-S and suspension or powder forms of elemental S fertilizers. Key words: Canola, elemental and sulphate S fertilizers, granular, suspension, oil and protein content, seed yield, S uptake

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